A SERIES OF NOVEL ONE-DIMENSIONAL POLYMERIC CLUSTERS [W4AG5S16](N)CENTER-DOT-N[LN(DMF)(8)] (LN=ND, PR AND LA) DERIVED FROM THE ASSEMBLY SYSTEM OF TETRATHIOTUNGSTATE AND SILVER-NITRATE - X-RAY CRYSTAL-STRUCTUREOF [W4AG5S16](N)CENTER-DOT-N[ND(DMF)(8)]

Authors
HUANG Q WU XT LU JX
Citation
Q. Huang et al., A SERIES OF NOVEL ONE-DIMENSIONAL POLYMERIC CLUSTERS [W4AG5S16](N)CENTER-DOT-N[LN(DMF)(8)] (LN=ND, PR AND LA) DERIVED FROM THE ASSEMBLY SYSTEM OF TETRATHIOTUNGSTATE AND SILVER-NITRATE - X-RAY CRYSTAL-STRUCTUREOF [W4AG5S16](N)CENTER-DOT-N[ND(DMF)(8)], Polyhedron, 16(5), 1997, pp. 833-838
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
5
Year of publication
1997
Pages
833 - 838
Database
ISI
SICI code
0277-5387(1997)16:5<833:ASONOP>2.0.ZU;2-B
Abstract
The title complexes have been obtained from reaction of ammonium tetra thiotungstate and silver nitrate in the presence of lanthanide nitrate in DMF and CH3CN. The one-dimensional polymeric cluster anionic struc ture can be viewed as square-type [W4Ag4S16](4-) fragments bridged by Ag+ cations. The valence and dimensions of the lanthanide-coordinated cations play significant roles in the assembly reaction of ammonium te trathiotungstate and silver nitrate. In addition, the IR and Raman spe ctra are discussed. Copyright (C) 1996 Elsevier Science Ltd