LOCAL-STRUCTURE OF SOLVATION OF NONPOLAR CHAINS IN NONPOLAR-SOLVENTS AT INFINITE DILUTION

Authors
TIKHONOV DA SARKISOV GN
Citation
Da. Tikhonov et Gn. Sarkisov, LOCAL-STRUCTURE OF SOLVATION OF NONPOLAR CHAINS IN NONPOLAR-SOLVENTS AT INFINITE DILUTION, Journal of structural chemistry, 37(4), 1996, pp. 639-644
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Journal of structural chemistry → ACNP
ISSN journal
00224766
Volume
37
Issue
4
Year of publication
1996
Pages
639 - 644
Database
ISI
SICI code
0022-4766(1996)37:4<639:LOSONC>2.0.ZU;2-X
Abstract
The SSOZ (site-site Ornstein-Zernike) equation is used to study the lo cal structure of solvation of linear nonpolar molecules in nonpolar so lvents. The atom-atomic interaction potentials are described by the Le nnard-Jones potential The chain-solvent atom-atomic pair correlation f unctions are calculated in relation to the chain length (number of ato ms), solvent density, and the ratio of the geometrical parameters of s olvent and chain atoms.