Aluminium sulfate is generally used as a primary coagulant in most mun
icipal water treatment plants. The sludge produced is often discharged
back into the river. Depending on the physicochemical properties of t
he river water, aluminium from the sludge will become soluble and form
various species that may be toxic to aquatic life. This study is an a
ttempt to look at the effect of alum sludge dumping on the distributio
n of various aluminium species in the Linggi River of Negeri Sembilan,
Malaysia, which is used as source of raw water for the Linggi Water T
reatment Plant. The result showed that the total aluminium concentrati
ons in the five sampling stations located upstream and downstream of t
he dumping point along the river were 0.48-1.14 mg L(-1), of which lab
ile aluminium was 0.37-0.56 mg L(-1) and non-labile aluminium was 0.12
-0.58 mg L(-1). Statistical analysis indicated that there was no signi
ficant difference in aluminium concentration in the water along the ri
ver. However, total aluminium concentration in the sediments increased
significantly downstream from the water plant, indicating that alumin
ium from the sludge dumping may accumulate in the sediment.