ON THE OXYGEN IN HEAVY-ION TRACKS HYPOTHESIS

Two well-known chemical systems, the Fricke (system I) and the Fricke + ethanol (system II), were irradiated with intermediate-energy C-12 a nd Ca-40 ion beams. A vertical beam allowed us to study radiation phen omena in the bulk of a stirred solution and in the motionless surface layer in contact with air. The G value of the formation of Fe3+ in sys tem II compared to system I allowed us to distinguish between oxygenat ed and hypoxic conditions in the reaction zone, i.e., in our case, in the vicinity of the heavy-ion path. Our results for nonstirred solutio ns that are open to air indicate an oxygen deficiency in the reaction zones even for medium-intensity ion fluences. The origin of this effec t is not completely clear at present. Nevertheless, it is evident that postulated mechanisms for the generation of O-2 in heavy-ion tracks a re not sufficient to keep an oxygenated condition in nonstirred soluti ons. We cannot exclude the possibility that the low oxygen enhancement ratio observed in experiments with high-LET radiation may arise, at l east partly, from an insufficiency rather than an excess of oxygen. (C ) 1995 by Radiation Research Society