STRUCTURE REFINEMENT OF MONOCLINIC V3S4

Authors
MUJICA C LLANOS J WITTKE O
Citation
C. Mujica et al., STRUCTURE REFINEMENT OF MONOCLINIC V3S4, Journal of alloys and compounds, 226(1-2), 1995, pp. 136-138
Citations number
9
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
226
Issue
1-2
Year of publication
1995
Pages
136 - 138
Database
ISI
SICI code
0925-8388(1995)226:1-2<136:SROMV>2.0.ZU;2-T
Abstract
The structure of monoclinic V3S4 was refined using single crystal X-ra y data. This modification crystallizes isostructural with Cr3S4, space group C2/m with a = 1263.8(2) pm, b = 329.4(1) pm, c = 587.8(1) pm an d beta = 115.68(1)degrees. The sulfur-metal distances are quite simila r to those reported for the hexagonal modification of V3S4. Neverthele ss, the monoclinic modification leaves smaller empty channels than tho se observed in the hexagonal modification.