S. Fujita et al., MECHANISM OF THE FORMATION OF PRECURSORS FOR THE CU ZNO METHANOL SYNTHESIS CATALYSTS BY A COPRECIPITATION METHOD/, Catalysis letters, 34(1-2), 1995, pp. 85-92
Precursors of Cu/ZnO catalysts with various Cu/Zn molar ratios were pr
epared by a coprecipitation method. It was found that amorphous copper
hydroxycarbonate and sodium zinc carbonate were intermediates for the
formation of various precursors such as hydrozincite, malachite and a
urichalcite. Aurichalcite having a high Cu/Zn ratio was prepared from
a mechanical mixture of these intermediates.