SOLVENT-FREE TELOMERIZATION OF BUTADIENE WITH WATER INTO OCTADIENOLS IN THE PRESENCE OF NONIONIC SURFACTANT - EFFICIENT MICELLAR CATALYSIS

Authors
MONFLIER E BOURDAUDUCQ P COUTURIER JL KERVENNAL J SUISSE I MORTREUX A
Citation
E. Monflier et al., SOLVENT-FREE TELOMERIZATION OF BUTADIENE WITH WATER INTO OCTADIENOLS IN THE PRESENCE OF NONIONIC SURFACTANT - EFFICIENT MICELLAR CATALYSIS, Catalysis letters, 34(1-2), 1995, pp. 201-212
Citations number
43
Categorie Soggetti
Chemistry Physical
Journal title
Catalysis letters → ACNP
ISSN journal
1011372X
Volume
34
Issue
1-2
Year of publication
1995
Pages
201 - 212
Database
ISI
SICI code
1011-372X(1995)34:1-2<201:STOBWW>2.0.ZU;2-7
Abstract
Telomerization of butadiene with water into 2,7-octadien-1-ol using a palladium-hydrosoluble phosphine system was investigated. The reaction was carried out without solvent in the presence of carbon dioxide and a nonionic surfactant. Promoted effect of neutral surfactant appeared above the critical micelle concentration and the conversion and the s electivity depended on the structure of nonionic surfactant hydrophili c part. The role of the nonionic surfactant is discussed.