Pa. Steward et al., STUDIES ON PERMEATION THROUGH POLYMER LATEX FILMS .1. FILMS CONTAINING NO OR ONLY LOW-LEVELS OF ADDITIVES, Polymer international, 38(1), 1995, pp. 1-12
A range of permeation techniques were employed to investigate the tran
sport mechanisms across polymer films cast from lattices containing ei
ther no or only low levels of water soluble leachates such as residual
surfactant from polymerisation or added plasticiser essential to film
formation. Hydrophilic pathways can provide a mechanism of transport,
in addition to partition into and solution-diffusion in the polymer p
hase. Loss of porosity by low T-g polymers on drying highlights the va
lue of solute probes in studying film morphology.