AL-27, H-1-NMR STUDIES OF SUPPORTED LIALH4 AND PD-LIALH4 AS REAGENTS FOR DECHLORINATION OF CHLOROBENZENE

Authors
SIMAGINA VI MASTIKHIN VM YAKOVLEV VA STOYANOVA IV LIKHOLOBOV VA
Citation
Vi. Simagina et al., AL-27, H-1-NMR STUDIES OF SUPPORTED LIALH4 AND PD-LIALH4 AS REAGENTS FOR DECHLORINATION OF CHLOROBENZENE, Journal of molecular catalysis. A, Chemical, 101(3), 1995, pp. 237-241
Citations number
12
Categorie Soggetti
Chemistry Physical
Journal title
Journal of molecular catalysis. A, Chemical → ACNP
ISSN journal
13811169
Volume
101
Issue
3
Year of publication
1995
Pages
237 - 241
Database
ISI
SICI code
1381-1169(1995)101:3<237:AHSOSL>2.0.ZU;2-D
Abstract
The reactivities of LiAlH4 and LiAlH4-Pd supported on porous carbon 'S ibunit' in dechlorination of chlorobenzene under mild conditions and t heir H-1, Al-27 high resolution solid state NMR MAS spectra are report ed. Supported hydrides demonstrate better reactivity compared with LiA lH4 in ether-toluene solution. H-1, and Al-27 NMR MAS spectra of suppo rted Pd-LiAlH4/Sibunit suggest the formation of complex hydrides on th e surface.