MOLECULAR-BEAM MASS-SPECTROMETRY OF VAN-DER-WAALS CLUSTERS - MASS-SPECTRUM OF HYDROGEN-SULFIDE DIMER

Authors
BUTKOVSKAYA NI VASILEV ES MOROZOV II
Citation
Ni. Butkovskaya et al., MOLECULAR-BEAM MASS-SPECTROMETRY OF VAN-DER-WAALS CLUSTERS - MASS-SPECTRUM OF HYDROGEN-SULFIDE DIMER, Russian chemical bulletin, 44(5), 1995, pp. 813-818
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
5
Year of publication
1995
Pages
813 - 818
Database
ISI
SICI code
1066-5285(1995)44:5<813:MMOVC->2.0.ZU;2-Q
Abstract
Hydrogen sulfide clusters generated by ultrasonic expansion of an H2S- Ar mixture into a vacuum were detected by electron impact mass spectro metry. The mass spectrum of the dimer, (H2S)(2), was obtained under co nditions of predominant dimerization. A mechanism of the formation of ions that involves intracluster reactions between the fragment ions of the monomer and the monomer molecule has been suggested.