NEW PACKING TYPE OF THE CONDUCTING LAYER IN THE STRUCTURE OF THE ORGANIC SEMICONDUCTOR (ET)(6)[PB(3)BR(9)PHCLME(2)CO], THE FIRST ET-BASED LEAD-CONTAINING SALT

Authors
DYACHENKO OA GRITSENKO VV SHILOV GV ZHILYAEVA EI LYUBOVSKAYA RN
Citation
Oa. Dyachenko et al., NEW PACKING TYPE OF THE CONDUCTING LAYER IN THE STRUCTURE OF THE ORGANIC SEMICONDUCTOR (ET)(6)[PB(3)BR(9)PHCLME(2)CO], THE FIRST ET-BASED LEAD-CONTAINING SALT, Russian chemical bulletin, 44(5), 1995, pp. 883-889
Citations number
21
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
5
Year of publication
1995
Pages
883 - 889
Database
ISI
SICI code
1066-5285(1995)44:5<883:NPTOTC>2.0.ZU;2-T
Abstract
A new organic semiconductor, (ET)(6)[Pb(3)Br(9)PhCiMe(2)CO], which is the first radical cation salt based on bis(ethylenedithio)tetrathiaful valene (ET) with a lead-containing anion, has been synthesized. The co mposition and crystal and molecular structure of this compound have be en established by X-ray structural analysis. The crystal structure can be described as a layer structure. A new alpha''' type of packing of ET radical cations has been found in the conducting layer. The anionic layer consists of [Pb3Br93-](n) polymeric anions and chlorobenzene an d acetone solvate molecules bonded to polymeric anions through Br...H- C hydrogen bonds.