NOVEL REACTION OF 1-ARYL-2-BROMODIAZENE 1-OXIDES WITH OLEFINS - SYNTHESIS OF 1-ARYL-2-(2-BROMOALKYL) DIAZENE 1-OXIDES

Authors
CHURAKOV AM TYURIN AY GONCHAROVA EL IOFFE SL STRELENKO YA TARTAKOVSKY VA
Citation
Am. Churakov et al., NOVEL REACTION OF 1-ARYL-2-BROMODIAZENE 1-OXIDES WITH OLEFINS - SYNTHESIS OF 1-ARYL-2-(2-BROMOALKYL) DIAZENE 1-OXIDES, Russian chemical bulletin, 44(5), 1995, pp. 890-896
Citations number
13
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
5
Year of publication
1995
Pages
890 - 896
Database
ISI
SICI code
1066-5285(1995)44:5<890:NRO11W>2.0.ZU;2-S
Abstract
The addition of 1-aryl-2-bromodiazene 1-oxides to olefins yields 1-ary l-2-(2-bromoalkyl)diazene 1-oxides (4). A radical mechanism of the rea ction has been suggested. Compounds 4 decompose to give bromohydrazone s of formaldehyde and aldehydes. The structural factors that affect th e rate of this process are discussed.