REACTIONS OF METHYLCHLORODISILANES WITH GRIGNARD-REAGENTS

Authors
SEMENOV VV LADILINA EY CHESNOKOVA TA ELISTRATOVA NK KURSKII YA MAKARENKO NP
Citation
Vv. Semenov et al., REACTIONS OF METHYLCHLORODISILANES WITH GRIGNARD-REAGENTS, Russian chemical bulletin, 44(5), 1995, pp. 927-930
Citations number
14
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
5
Year of publication
1995
Pages
927 - 930
Database
ISI
SICI code
1066-5285(1995)44:5<927:ROMWG>2.0.ZU;2-V
Abstract
Reactions of Cl(2)MeSiSiMeCl(2) with RMgCl make it possible to obtain and isolate pure disilanes containing a smaller number of functional g roups, namely, RMeClSiSiMeCl(2) (R = Ph), RMeClSiSiMeRCl (R = Pr-i, Ph ), and R(2)MeSiSiMeRCl (R = Bu(i)). The reaction of Cl(2)MeSiSiMeCl(2) with Bu(n)MgCl is the feast selective. The chlorides obtained were re duced with LiAlH4 into the corresponding hydrides.