2-STEP OXIDATIVE ONE-POT FUNCTIONALIZATION OF 2-BENZYLIDENE-1-TETRALONE IN THE PD-II CU-II/NA2CO3-MEOH SYSTEM - A NOVEL ROUTE TO 2-(ALPHA-METHOXY)BENZYL-1,4-NAPHTHOQUINONE/

Authors
NIKANOROV VA ROGACHEV AD ORLOV VD
Citation
Va. Nikanorov et al., 2-STEP OXIDATIVE ONE-POT FUNCTIONALIZATION OF 2-BENZYLIDENE-1-TETRALONE IN THE PD-II CU-II/NA2CO3-MEOH SYSTEM - A NOVEL ROUTE TO 2-(ALPHA-METHOXY)BENZYL-1,4-NAPHTHOQUINONE/, Russian chemical bulletin, 44(5), 1995, pp. 958-959
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
5
Year of publication
1995
Pages
958 - 959
Database
ISI
SICI code
1066-5285(1995)44:5<958:2OOFO2>2.0.ZU;2-C
Abstract
A novel two-step oxidative one pot functionalization of 2-benzylidene- 1-tetralone by its reaction with Na2PdCl4 in the presence of CuCl2 and Na2CO3 (in 1 : 1 : 2 : 5 molar ratio)in MeOH was discovered. The reac tion yields 2-(alpha-methoxy)benzyl-1,4-naphthoquinone.