Polymer ferroelectric films were prepared by dispersing TGS powder in
polystyrene. Permittivity versus temperature plots exhibit a peak at a
round the transition temperature of TGS. The peak gets suppressed with
increasing frequency and the trend continues up to microwave frequenc
ies. We observed that the dielectric constant of films at microwave fr
equency stays close to the dielectric constant of polystyrene. The dom
ain structure of TGS crystals essentially seems to affect their dielec
tric properties. Single domain films exhibit a higher spontaneous pola
rization and a higher coercive field.