The use of an electrolytic respirometer for characterization of chemic
al compounds and wastewater was studied. From the BOD curves generated
by the respirometer, the first order biokinetic constant(K), ultimate
BOD (BODu) and adaptation period were estimated. The estimated ultima
te BOD values of the known chemical compounds were very close to the t
heoretical oxygen demand values. Using K values, the relative biodegra
dability of the chemicals could be compared while the adaptation perio
d for each compound could vary with the type of seed micro-organisms u
sed. It was found that BOD5 values determined by the conventional meth
od have no or very little, if any, meaning as far as the biological ch
aracteristics of industrial wastewaters are concerned. The BOD curves
for wastewaters consisting of 2 or 3 different compounds could be divi
ded into several stages while those for the combined wastewaters could
be expressed as one curve.