COINTERCALATION OF SODIUM AND ITS HALIDES INTO GRAPHITE

Citation
A. Herold et al., COINTERCALATION OF SODIUM AND ITS HALIDES INTO GRAPHITE, Comptes rendus de l'Academie des sciences. Serie II. Mecanique, physique, chimie, astronomie, 321(2), 1995, pp. 61-67
Citations number
8
Categorie Soggetti
Multidisciplinary Sciences
ISSN journal
12518069
Volume
321
Issue
2
Year of publication
1995
Pages
61 - 67
Database
ISI
SICI code
1251-8069(1995)321:2<61:COSAIH>2.0.ZU;2-Q
Abstract
New dark blue ternary intercalation compounds have been synthesized by heating graphite with liquid sodium in presence of a halide in the so lid state. Sodium has intercalated with its chloride leading to compou nds of stages 4 and 3, with its bromide to a third stage phase; sodium and iodine cointercalation has led to second stage products often inv olving a mixture of phases. The composition, structure, stability and electrical resistivity of the products have been studied.