CHIRAL 2-ALKOXY-1,3-BUTADIENES - SYNTHESIS AND FACE-SELECTIVITY IN DIELS-ALDER REACTIONS

Authors
BARLUENGA J TOMAS M SUAREZSOBRINO A LOPEZ LA
Citation
J. Barluenga et al., CHIRAL 2-ALKOXY-1,3-BUTADIENES - SYNTHESIS AND FACE-SELECTIVITY IN DIELS-ALDER REACTIONS, Journal of the Chemical Society, Chemical Communications, (17), 1995, pp. 1785-1786
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
17
Year of publication
1995
Pages
1785 - 1786
Database
ISI
SICI code
0022-4936(1995):17<1785:C2-SAF>2.0.ZU;2-9
Abstract
Chiral 2-alkoxy-1,3-butadienes are prepared from chiral alcohols, prop -2-ynyltriphenylphosphonium bromide and aldehydes; they undergo [4 + 2 ] cycloadditions to carbo- and hetero-dienophiles with moderate to hig h face-selectivity.