PHOTOCHEMISTRY OF AQUEOUS TETRATHIOANTIMO NATE(V)

Authors
KUNKELY H VOGLER A
Citation
H. Kunkely et A. Vogler, PHOTOCHEMISTRY OF AQUEOUS TETRATHIOANTIMO NATE(V), Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 50(8), 1995, pp. 1155-1157
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
50
Issue
8
Year of publication
1995
Pages
1155 - 1157
Database
ISI
SICI code
0932-0776(1995)50:8<1155:POATN>2.0.ZU;2-0
Abstract
The electronic spectrum of [SbS4](3-) in 10(-3) M NaOH displays an abs orption band at lambda(max) = 285 nm which is assigned to a ligand-to- metal charge transfer (LMCT) transition. Upon LMCT excitation [SbS4](3 -) undergoes an intramolecular redox reaction with the formation of [S bS3](3-) and elemental sulfur (phi = 0.11 at lambda(irr) = 333 nm).