SYNTHESES AND PROPERTIES OF THE GOLD(I) COMPLEXES WITH BULKY THIOLATES [AU(SR)](6) AND [AU(SR)(PPH(3))] (R=C(6)H(2)ME(3)-2,4,6 OR C6H2PR3I-2,4,6), AND THE MOLECULAR-STRUCTURE OF [AU(SC6H2PR3I-2,4,6)(PPH(3))]

Authors
TONG YY POMBEIRO AJL HUGHES DL RICHARDS RL
Citation
Yy. Tong et al., SYNTHESES AND PROPERTIES OF THE GOLD(I) COMPLEXES WITH BULKY THIOLATES [AU(SR)](6) AND [AU(SR)(PPH(3))] (R=C(6)H(2)ME(3)-2,4,6 OR C6H2PR3I-2,4,6), AND THE MOLECULAR-STRUCTURE OF [AU(SC6H2PR3I-2,4,6)(PPH(3))], Transition metal chemistry, 20(4), 1995, pp. 372-375
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
20
Issue
4
Year of publication
1995
Pages
372 - 375
Database
ISI
SICI code
0340-4285(1995)20:4<372:SAPOTG>2.0.ZU;2-M
Abstract
[Au(SR)](6) (R = C(6)H(2)Me(3)-2,4,6 or C6H2Pr3i-2,4,6), prepared by t reatment of chloroauric acid in water with thiodiglycol followed by re action with the appropriate thiol(HSR) in CHCl3, can add PPh(3) in CH2 Cl2 to give [Au(SR)(PPh(3))], which, alternatively, can be obtained fr om reaction of [AuCl(PPh(3))] in THF with HSR in the presence of KOH-E tOH. The molecular structure of [Au(SC6H2Pr3i-2,4,6) (PPh(3))] has bee n determined by X-ray diffraction analysis.