M. Yamaguchi et K. Morigaki, INTERFACE DEFECTS AND THEIR ROLES IN LIGHT-INDUCED PHENOMENA IN N-SI-H A-SI1-XNX-H MULTILAYERS/, Physical review. B, Condensed matter, 55(4), 1997, pp. 2378-2383
The interface defects in the n-Si:H/a-Si1-xNx:H multilayer have been e
xamined from photoluminescence (PL) and optically detected magnetic re
sonance (ODMR) measurements, particularly for a-Si:H/a-Si0.6N0.4:H mul
tilayers fabricated by varying the interrupting interval of alternatin
g two gases, i,e., SiH4 diluted to 10% in H-2 and a mixture gas of SiH
4 (10% in H-2) and pure NH3. The results of the PL and ODMR measuremen
ts are discussed in terms of three kinds of interface defects, i.e., s
ilicon dangling bonds, T-3(0), separate T-3(+)-N-2(-) pair defects (E
centers), and close T-3(+)-N-2(-) pair defects (E centers), where T-3
(+) and N-2(-) designate the positively charged threefold-coordinated
silicon atom and negatively charged twofold-coordinated nitrogen atom,
respectively. The light-induced effect on PL and ODMR was also discus
sed in terms of creation of the interface defects by prolonged illumin
ation. These investigations allow us to elucidate the nature of the in
terface defects in those multilayers.