A new technique has been developed for measuring electron drift mobili
ty in crystals on a microscopic scale through its effect on muonium (m
u(+)e(-)) atom formation via transport of electrons to thermalized pos
itive muons (mu(+)). Electron transport mechanisms are shown to be fun
damentally different in the alpha and beta phases of solid nitrogen, g
iving at least 5 orders of magnitude difference in electron mobilities
. Contrary to reported results of macroscopic time-of-fight measuremen
ts, excess electrons appear to be delocalized in alpha-N-2.