STABILIZATION OF REACTANTS IN A WEAKLY-BOUND COMPLEX - OH-H-2 AND OH-D-2

Authors
LOOMIS RA LESTER MI
Citation
Ra. Loomis et Mi. Lester, STABILIZATION OF REACTANTS IN A WEAKLY-BOUND COMPLEX - OH-H-2 AND OH-D-2, The Journal of chemical physics, 103(10), 1995, pp. 4371-4374
Citations number
33
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
103
Issue
10
Year of publication
1995
Pages
4371 - 4374
Database
ISI
SICI code
0021-9606(1995)103:10<4371:SORIAW>2.0.ZU;2-A
Abstract
Binary complexes of OH X(2) Pi and H-2/D-2 have been stabilized in a s hallow well below the activation barrier to the hydrogen abstraction r eaction and identified by laser-induced fluorescence in the OH A (2) S igma(+)-X (2) Pi 1-0 spectral region. The characteristics of the OH (X (2) Pi, A (2) Sigma(+)) + H-2/D-2 potentials are in accord with ab in itio predictions. (C) 1995 American Institute of Physics.