Cq. Sun et al., SELECTIVE POTENTIOMETRIC DETERMINATION OF COPPER(II) IONS BY USE OF AMOLECULAR DEPOSITION FILM ELECTRODE BASED ON WATER-SOLUBLE COPPER PHTHALOCYANINE, Analytica chimica acta, 312(2), 1995, pp. 207-212
A novel copper(II)-selective electrode was produced based on a molecul
ar deposition technique in which water-soluble copper phthalocyanine t
etrasulfonate was alternatively deposited with a bipolar pyridine salt
(PyC(6)BPC(6)Py) on a 3-mercaptopropionic acid modified Au electrode.
The potentiometric response is independent on pH of the solution betw
een pH 1 and 5, while it is dependent on the nature of the medium. The
electrode has a linear dynamic range between 1 x 10(-5) and 0.1 mol l
(-1) with a Nernstian slope of 29 mV/decade concentration and a detect
ion limit of 7 x 10(-6) mol l(-1) in acetate buffer (0.2 mol l(-1), pH
4.5). Except for Fe2+, Fe3+ and Co2+, Other common inorganic cations
do not interfere in the determination of copper(II). The electrode has
the advantages of low resistance, short conditioning time and fast re
sponse.