J. Pietsch et al., PESTICIDES AND OTHER ORGANIC MICRO POLLUTANTS IN THE RIVER ELBE, Fresenius' journal of analytical chemistry, 353(1), 1995, pp. 75-82
The main components of organic micro pollution regularly found in the
river Elbe, belong to the wide spectrum of pesticides, nitro and chlor
o benzenes and the chelating agents, especially ethylenediaminetetraac
etic acid (EDTA). The level of organic micro pollution with pesticides
and the other organic micro pollutants in the upper and middle reache
s of the river Elbe between Schmilka and Wittenberge was determined ov
er a period of nearly three years. Four sample preparation methods (SP
E: solid-phase extraction and LLE: liquid-liquid extraction both with
and without derivatization) have been used to analyze a wide spectrum
of pesticides with different polarities by GC/ECD, NPD and MS. The pes
ticide pollution caused by the triazines decreases significantly from
0.35 mu g/l (mean value) in 1992 up to 0.15 mu g/l (mean value) in 199
4. The correlation with the river water Row shows the diffuse characte
r of the triazine input. In the last year of the pesticide screening a
change to the more polar substances such as phenoxyalkanoic acid and
nitrophenol pesticides as well as chloralkanoic acid pesticides have b
een noticed. The origin of trichloroacetic acid (TCA) can be explained
by the waste influence, supported by the good correlation of the TCA
course with the chloroform concentrations determined.