ASYMMETRIC [2,3]-WITTIG REARRANGEMENTS WITH CHIRAL, PHOSPHORUS ANION-STABILIZING GROUPS

Citation
Se. Denmark et Pc. Miller, ASYMMETRIC [2,3]-WITTIG REARRANGEMENTS WITH CHIRAL, PHOSPHORUS ANION-STABILIZING GROUPS, Tetrahedron letters, 36(37), 1995, pp. 6631-6634
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
36
Issue
37
Year of publication
1995
Pages
6631 - 6634
Database
ISI
SICI code
0040-4039(1995)36:37<6631:A[RWCP>2.0.ZU;2-H
Abstract
The [2,3]-Wittig rearrangement of a chirally-modified phosphorus stabi lized anion proceeds readily and with excellent diastereo- and enantio selectivity for allyloxymethyl and (Z)-2-butenyloxymethyl derivatives.