DEPENDENCE OF THE ENANTIOSELECTIVITY ON THE NATURE OF THE BASE IN A HORNER-WADSWORTH-EMMONS REACTION LEADING TO VINYL SULFOXIDES

Authors
CARDELLICCHIO C IACUONE A NASO F
Citation
C. Cardellicchio et al., DEPENDENCE OF THE ENANTIOSELECTIVITY ON THE NATURE OF THE BASE IN A HORNER-WADSWORTH-EMMONS REACTION LEADING TO VINYL SULFOXIDES, Tetrahedron letters, 36(36), 1995, pp. 6563-6566
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
36
Year of publication
1995
Pages
6563 - 6566
Database
ISI
SICI code
0040-4039(1995)36:36<6563:DOTEOT>2.0.ZU;2-0
Abstract
The enantioselectivity of the HWE synthesis of chiral methyl (Z)- and (E)-3-p-tolylsulfinylpropenoate was found to depend upon the nature of the base, the e.e. values being in the range 5-->98%.