ECLIPSED EXOCYCLIC CARBON-OXYGEN BONDS IN THE HEXAMETHYL ETHER OF SCYLLO-INOSITOL - X-RAY CRYSTALLOGRAPHIC AND NMR-STUDIES

Authors
ANDERSON JE ANGYAL SJ CRAIG DC
Citation
Je. Anderson et al., ECLIPSED EXOCYCLIC CARBON-OXYGEN BONDS IN THE HEXAMETHYL ETHER OF SCYLLO-INOSITOL - X-RAY CRYSTALLOGRAPHIC AND NMR-STUDIES, Carbohydrate research, 272(2), 1995, pp. 141-148
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
272
Issue
2
Year of publication
1995
Pages
141 - 148
Database
ISI
SICI code
0008-6215(1995)272:2<141:EECBIT>2.0.ZU;2-#
Abstract
Hexa-O-methyl-scyllo-inositol was synthesized and its crystal structur e was determined by X-ray diffraction. As predicted by calculations, e ach oxygen-methyl bond eclipses the adjacent carbon-hydrogen bond. NMR studies show that the same conformation predominates in solution.