Electromagnetic waves in the system ''dielectric substrate-layer of ad
sorbed molecules'' were considered for the case, when in the adsorbed
layer of molecules a periodic polarization structure is formed. For th
ese systems the electrodynamic Green function was found. Dispersion cu
rves for s-and p-polaritons, localized on the surface of the solid wit
h the adsorbed molecular layer were calculated. The mechanism of forma
tion of a ''band structure'' at the spectrum of these modes was studie
d.