MULTINUCLEAR, VARIABLE-TEMPERATURE NMR-STUDY OF HYDROGEN-BONDING IN 2ORTHO-MANNICH BASES

Authors
SITKOWSKI J STEFANIAK L ROSPENK M SOBCZYK L WEBB GA
Citation
J. Sitkowski et al., MULTINUCLEAR, VARIABLE-TEMPERATURE NMR-STUDY OF HYDROGEN-BONDING IN 2ORTHO-MANNICH BASES, Journal of physical organic chemistry, 8(7), 1995, pp. 463-467
Citations number
7
Categorie Soggetti
Chemistry Physical","Chemistry Inorganic & Nuclear
Journal title
Journal of physical organic chemistry → ACNP
ISSN journal
08943230
Volume
8
Issue
7
Year of publication
1995
Pages
463 - 467
Database
ISI
SICI code
0894-3230(1995)8:7<463:MVNOHI>2.0.ZU;2-L
Abstract
H-1 and C-13 NMR data for 2-diethylaminomethyl-3,4,6-tri- and -tetrach lorophenols in CH2Cl2 solutions at a variety of temperatures are repor ted, The results are consistent with intramolecular hydrogen bonding a nd proton transfer as shown in the structure 3. Concentration dependen ce of the NMR data for the perchloro compound shows an additional hydr ogen bonding process attributed to the solute self-association. The H- 1, C-13 and and N-15 NMR data support the proposed proton transfer str ucture,