Dc. Nambiar et Vm. Shinde, SEPARATION OF CADMIUM SALICYLATE BY SOLVENT-EXTRACTION USING TRIS(2-ETHYLHEXYL) PHOSPHATE, Bulletin of the Chemical Society of Japan, 68(8), 1995, pp. 2277-2279
Tris(2-ethylhexyl) phosphate (T2EHP) is used for the extraction of cad
mium salicylate. The experimental conditions are established and the p
robable extractable species is ascertained by logo-log C plots. Microg
ram amounts of cadmium are determined in the Tris(2-ethylhexyl) phosph
ate phase with 1-(2-pyridylazo)-2-naphthol as the chromogenic agent. T
he proposed method is used for the separation of cadmium(II) from zinc
(II), mercury(II), lead(II), bismuth(III), antimony(III), and thallium
(III) and used for the estimation of cadmium in industrial waste water
, kidney stone, cigarettes, and alloy samples.