EASY METALATION OF THE SUBSTITUTED DIMETHYL SULFIDE MESCH(2)R (R=C(O)OET) BY PALLADIUM ACETATE AND CHARACTERIZATION OF THE TRINUCLEAR MIXED-SPHERE [PD-3(MU-O(2)CME)(3)(MU-MESCHR)(3)] COMPLEX

Authors
BASATO M GRASSI A VALLE G
Citation
M. Basato et al., EASY METALATION OF THE SUBSTITUTED DIMETHYL SULFIDE MESCH(2)R (R=C(O)OET) BY PALLADIUM ACETATE AND CHARACTERIZATION OF THE TRINUCLEAR MIXED-SPHERE [PD-3(MU-O(2)CME)(3)(MU-MESCHR)(3)] COMPLEX, Organometallics, 14(9), 1995, pp. 4439-4442
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
14
Issue
9
Year of publication
1995
Pages
4439 - 4442
Database
ISI
SICI code
0276-7333(1995)14:9<4439:EMOTSD>2.0.ZU;2-0
Abstract
Palladium acetate reacts with the weak carbon. acid MeSCH(2)R (R = C(O )OEt) to give [Pd-3(mu-O(2)CMe)(3)(mu-MeSCHR)(3)] (1), characterized b y X-ray crystallography. The MeSCHC(O)OEt(-) anion acts as a bidentate Ligand binding two palladium atoms via a (Me)SCH(R) bridge, in which the methine carbon. is chiral. Complex 1 is the first mixed-sphere pal ladium complex in which the solid-state nuclearity and structure of pa lladium acetate is retained.