MOLECULAR AXIS ORIENTATION BY THE BRUTE FORCE METHOD

Citation
Jc. Loison et al., MOLECULAR AXIS ORIENTATION BY THE BRUTE FORCE METHOD, Journal of physical chemistry, 99(37), 1995, pp. 13591-13596
Citations number
36
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
99
Issue
37
Year of publication
1995
Pages
13591 - 13596
Database
ISI
SICI code
0022-3654(1995)99:37<13591:MAOBTB>2.0.ZU;2-5
Abstract
Using a strong electric field, it is possible to orient polar molecule s in their lowest rotational states. This ''brute force'' technique, i ntroduced by Loesch, is very powerful and has many applications. In th is paper, we recall the general theory of the effect, i.e., the proper ties of the pendular states introduced by Friedrich and Herschbach. We then discuss the effects of hyperfine structure on the orientation pr ocess. Finally, we discuss the optimization of an oriented molecular b eam of ICl.