AQUEOUS-SOLUTION OF SODIUM-SULFATE - DETERMINATION OF THE DISSOLUTIONENTHALPY AT 25, 27.5 AND 45-DEGREES-C

Authors
HUBERT N BOUROUKBA M SCHUFFENECKER L
Citation
N. Hubert et al., AQUEOUS-SOLUTION OF SODIUM-SULFATE - DETERMINATION OF THE DISSOLUTIONENTHALPY AT 25, 27.5 AND 45-DEGREES-C, Thermochimica acta, 259(1), 1995, pp. 41-48
Citations number
5
Categorie Soggetti
Chemistry Analytical
Journal title
Thermochimica acta → ACNP
ISSN journal
00406031
Volume
259
Issue
1
Year of publication
1995
Pages
41 - 48
Database
ISI
SICI code
0040-6031(1995)259:1<41:AOS-DO>2.0.ZU;2-R
Abstract
The dissolution enthalpy of sodium sulfate in water was measured until saturation at 24.4, 27.5 and 44.3 degrees C using a C80D differential calorimeter (Setaram). The experimental data were fitted using Pitzer 's ion interaction model and the value of the dissolution enthalpy per mole of salt at infinite dilution was found at each temperature, by t reating (Delta(diss)H)(infinity) as an adjustable parameter.