EXCESS VOLUMES AND VISCOSITIES OF THE TERNARY-SYSTEM WATER-TRIFLUOROETHANOL-TETRAETHYLENE GLYCOL DIMETHYL ETHER AT 303.15 K

Citation
F. Olive et al., EXCESS VOLUMES AND VISCOSITIES OF THE TERNARY-SYSTEM WATER-TRIFLUOROETHANOL-TETRAETHYLENE GLYCOL DIMETHYL ETHER AT 303.15 K, Thermochimica acta, 259(1), 1995, pp. 57-70
Citations number
9
Categorie Soggetti
Chemistry Analytical
Journal title
ISSN journal
00406031
Volume
259
Issue
1
Year of publication
1995
Pages
57 - 70
Database
ISI
SICI code
0040-6031(1995)259:1<57:EVAVOT>2.0.ZU;2-0
Abstract
Densities and kinematic viscosities of the ternary mixture water-trifl uoroethanol-tetraethylene glycol dimethyl ether have been measured at 303.15K and atmospheric pressure over the entire range of compositions , Excess molar volumes and excess viscosities were obtained from the e xperimental results. The excess volumes were negative and excess visco sities were positive, indicating the asymmetric composition dependence of the two thermodynamic properties. The excess volumes have been cor related, by the Redlich-Kister equation and the kinematic viscosity da ta have been fitted using the Stephan and Heckenberger correlation.