REVERSE COPE ELIMINATION-REACTIONS .2. APPLICATION TO SYNTHESIS(1)

Authors
CIGANEK E
Citation
E. Ciganek, REVERSE COPE ELIMINATION-REACTIONS .2. APPLICATION TO SYNTHESIS(1), Journal of organic chemistry, 60(18), 1995, pp. 5803-5807
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
60
Issue
18
Year of publication
1995
Pages
5803 - 5807
Database
ISI
SICI code
0022-3263(1995)60:18<5803:RCE.AT>2.0.ZU;2-R
Abstract
Intramolecular addition of N,N-disubstitute hydroxylamines to unactiva ted olefins was used to prepare an indolizine, a pyrrolo[2,1-a]isoquin oline, a 1,8-diazaspiro[4.5]decane, a cyclopenta[b]pyrrole, and an iso indoline. A pyrrolizine and a 1-azabicyclo[2.2.1] heptane were synthes ized from acyclic precursors by two consecutive reverse Cope eliminati on reactions.