We present a magneto-optical study of ZnSe/Zn1-x-yCdxMnySe quantum-wel
l structures' in which a suitable choice of the Cd composition leads t
o a system that is type I at zero magnetic field. When a magnetic fiel
d is applied perpendicular to the layers of the structure, the band ed
ges split in such a way as to make the upper sigma(-)(+1/2, +3/2) exci
ton transition type II, while the ground state sigma(+) (-1/2,-3/2) ex
citon component remains type I at all field values. This alignment red
uces the probability for carrier relaxation from the higher-energy exc
iton component and opens the possibility of hole-spin population inver
sion via optical pumping.