The condensation of chemical species of high molecular mass such as me
thane, ammonia, and water can inhibit convection in the hydrogen-heliu
m atmospheres of the giant planets. Convection is inhibited in Uranus
and Neptune when methane reaches an abundance of about 15 times the so
lar value and in Jupiter and Saturn if the abundance of water is more
than about five times the solar value. The temperature gradient conseq
uently becomes superadiabatic, which is observed in temperature profil
es inferred from radio-occultation measurements. The planetary heat fl
ux is then likely to be transported by another mechanism, possibly rad
iation in Uranus, or diffusive convection.