REACTION OF CHLORINE NITRATE WITH CF3I - ISOLATION OF TRIFLUORMETHYLCHLOROIODINENITRATE CF3I(CL)ONO2 AND THE CRYSTAL-STRUCTURE OF TRIFLUORMETHYLIODINEDINITRATE CF3I(ONO2)(2)

Authors
MINKWITZ R HERTEL T PREUT H
Citation
R. Minkwitz et al., REACTION OF CHLORINE NITRATE WITH CF3I - ISOLATION OF TRIFLUORMETHYLCHLOROIODINENITRATE CF3I(CL)ONO2 AND THE CRYSTAL-STRUCTURE OF TRIFLUORMETHYLIODINEDINITRATE CF3I(ONO2)(2), Zeitschrift fur anorganische und allgemeine Chemie, 621(9), 1995, pp. 1552-1557
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
621
Issue
9
Year of publication
1995
Pages
1552 - 1557
Database
ISI
SICI code
0044-2313(1995)621:9<1552:ROCNWC>2.0.ZU;2-P
Abstract
CF3I reacts with ClONO2 to Iodine(III)-compounds. After an addition CF 3I(Cl)ONO2 is isolated and characterized by vibrational spectra. With surplus ClONO2 it is formed CF3I(ONO2)(2). CF3I(ONO2)(2) crystallizes monoclinic in the space group P2(i)/c with the cell parameters a = 102 4.3(6)pm, b= 873.5(6) pm, c = 873.4(6)pm and Z = 4. We measered follow ing bonding distances: I-O: 207.3(3) and 220.8(2) pm, I-C: 221.1(4)pm and N-O: from 119.1(4) to 141.5(3) pm. Through an intermolecular I ... O-contact the central iodine becomes a distorted plane geometry.