This article compares the nature of phosphorus antisite defects in as-
grown and neutron irradiated GaP crystals. Electron spin resonance stu
dies indicate that these defects in both kinds of crystals have identi
cal close neighbors consisting of four phosphorus atoms. Neutron irrad
iation of GaP introduced an additional defect (called WA1), which is l
inked to a gallium antisite. Characteristic absorption bands and condu
ctivity of neutron irradiated CaP crystals are discussed as well. (C)
1995 American Institute of Physics.