Femtosecond pulses were used to study the photoexcitation dynamics and
transient photoinduced dichroism in polydiacetylene 4BCMU film. Ultra
fast photoinduced dichroism acid optical Kerr gate response were obser
ved. These measurements allowed estimation of the diffusion constant (
D similar to 0.1 cm(2)/s), nonlinear index of refraction (n2 similar t
o 10(-8) esu), and third-order susceptibility (Delta(chi)((3))similar
to 6 X 10(-10) esu), in the film. (C) 1995 American Institute of Physi
cs.