Ca. Grattoni et al., DETERMINATION OF RELATIVE WETTABILITY OF POROUS SANDSTONES BY IMBIBITION STUDIES, Journal of chemical technology and biotechnology, 64(1), 1995, pp. 17-24
The effective wettability of consolidated sandstone rocks has been det
ermined using the Washburn equation by measuring the rate of imbibitio
n of water, ethanol and their mixtures into cores and thin rectangular
sections. The rocks behaved as low energy surfaces with a critical su
rface energy of spreading, as defined by Zisman, of 28 mN m(-1). This
behaviour is believed to be caused by clay particles or organic materi
al present on the pore surfaces. A discussion of the validity and limi
tations of the Washburn equation for obtaining effective wettabilities
in consolidated porous media is presented. The general conclusion is
that effective wettability depends on the preparation and general cond
itions of the samples.