NITROGEN-PHOSPHORUS MULTIPLE BOND VIBRATIONAL ASSIGNMENTS IN THE INFRARED AND RAMAN

Authors
BURFORD N CLYBURNE JAC SILVERT D WARNER S WHITLA WA DARVESH KV
Citation
N. Burford et al., NITROGEN-PHOSPHORUS MULTIPLE BOND VIBRATIONAL ASSIGNMENTS IN THE INFRARED AND RAMAN, Inorganic chemistry, 36(3), 1997, pp. 482
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
36
Issue
3
Year of publication
1997
Database
ISI
SICI code
0020-1669(1997)36:3<482:NMBVAI>2.0.ZU;2-Y
Abstract
FT-Infrared and FT-Raman spectra are presented for a series of MesNP derivatives. N-15-labeled samples and comparisons between compounds al low for reliable assignment of NP stretching frequencies. The observed isotopic shift is consistent with calculated values, and assignments are supported by the observation of a relationship between the relativ e Raman intensity of the NP stretch and the bond angle at the nitrogen center (C-N-P).