MEASUREMENT OF THE STATE-SPECIFIC DIFFERENTIAL CROSS-SECTION FOR THE H-2-]HD(V'=4, J'=3)+D REACTION AT A COLLISION ENERGY OF 2.2 EV(D)

Authors
XU H SHAFERRAY NE MERKT F HUGHES DJ SPRINGER M TUCKETT RP ZARE RN
Citation
H. Xu et al., MEASUREMENT OF THE STATE-SPECIFIC DIFFERENTIAL CROSS-SECTION FOR THE H-2-]HD(V'=4, J'=3)+D REACTION AT A COLLISION ENERGY OF 2.2 EV(D), The Journal of chemical physics, 103(12), 1995, pp. 5157-5160
Citations number
47
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
103
Issue
12
Year of publication
1995
Pages
5157 - 5160
Database
ISI
SICI code
0021-9606(1995)103:12<5157:MOTSDC>2.0.ZU;2-Y
Abstract
HI and D-2 are coexpanded into a vacuum chamber. The photolysis of HI at 212.8 nm-initiates the H+D-2 reaction. The HD(v=4,J'=3) velocity di stribution is determined by analyzing the time-of-flight profile of HD + ions produced by delayed pulsed field ionization of long-lived Rydbe rg states. The angular distribution is deduced using the law of cosine s (photoloc technique). (C) 1995 American Institute of Physics.