MOMENTUM-TRANSFER-RESOLVED ELECTRON-ENERGY-LOSS SPECTROSCOPY OF BABIO3 - ANISOTROPIC DISPERSION OF THRESHOLD EXCITATION AND OPTICALLY FORBIDDEN TRANSITION
Yy. Wang et al., MOMENTUM-TRANSFER-RESOLVED ELECTRON-ENERGY-LOSS SPECTROSCOPY OF BABIO3 - ANISOTROPIC DISPERSION OF THRESHOLD EXCITATION AND OPTICALLY FORBIDDEN TRANSITION, Physical review letters, 75(13), 1995, pp. 2546-2549
Momentum-transfer-resolved electron energy loss spectroscopy of the va
lence band transitions in BaBiO3 has revealed for the first time that
dispersion of the excitation at the optical gap (similar to 2 eV) and
an optically forbidden transition at 4.5 eV are all anisotropic along
[100] and [110]. The anisotropic dispersion of the threshold excitatio
n cannot be described by a simple charge density wave picture but can
be explained by a small exciton model proposed in this paper. The opti
cally forbidden transition is found to agree well with a proposed mole
cular orbital model, where the transition is assigned as the excitatio
n from the O 2p sigma nonbonding states to the empty Bi 6s state.