Ks. Sorbie et al., THE EXTENDED WASHBURN EQUATION AND ITS APPLICATION TO THE OIL WATER PORE DOUBLET PROBLEM/, Journal of colloid and interface science, 174(2), 1995, pp. 289-301
The equations of capillary rise or wetting-phase imbibition into a cyl
indrical capillary are frequently described by the Washburn equation.
From this starting point, the familiar pore doublet model for imbibiti
on into a wide/narrow pair of pores has been developed. This simple an
alytically soluble model can afford insights into the physics of immis
cible water/oil displacements in porous media, which are of importance
to waterflooding of oil reservoirs. Here, we reexamine the basis of b
oth the Washburn equation and the formulation of the pore doublet mode
l by incorporating a more rigorous treatment of the fluid mechanics. W
e have extended equations previously proposed by Szekely et al, to des
cribe water/oil displacement in a capillary and it transpires that cer
tain additional inertial terms, which appear in the full formulation o
f the capillary displacement problem, may be particularly important at
the pore size and aspect ratio commonly encountered within porous med
ia. The main result of this additional physics is that the pore fillin
g time and the relative filling order of large and small pores may cha
nge since these quantities depend on the pore aspect ratio in tire ext
ended formulation. When this fuller formulation is embedded within the
extended pore doublet model, we find that the modified equations lead
to different findings for certain cases, compared with previous well-
known (analytical) solutions. The original pore doublet model is fully
characterised by three quantities, the aspect ratio, r(2)/L, the rati
o of capillary radii, r(1)/r(2), and the fluid ''supply,'' i.e., free
supply or restricted supply, which is characterized by a velocity, V-2
(0). In the extended pore doublet model there is a fourth governing qu
antity, the pore scale Reynolds number, N-Re, which describes the iner
tial terms in the extended Washburn equation. The resulting coupled di
fferential equations for the extended pore doublet model do not admit
an analytical solution and must be solved numerically. Under certain c
onditions of very restricted supply of wetting fluid (low V-2(0)), the
extended model agrees very closely with the conventional pore doublet
results. However, there are cases which are common at the pore scale
(and pore aspect ratio) where significant differences are seen. The re
levance of these findings to the modeling of imbibition processes with
in network models of porous media is discussed. (C) 1995 Academic Pres
s, Inc.