Gf. Cerofolini et N. Re, EXTRACTING THE ENERGY-DISTRIBUTION FUNCTIONS OF HETEROGENEOUS SURFACES FROM THEIR DESORPTION-KINETICS, Journal of colloid and interface science, 174(2), 1995, pp. 428-440
The desorption kinetics from heterogeneous surfaces contain informatio
n on energy heterogeneity. Mathematical methods for extracting the ene
rgy distribution function from desorption kinetics are developed in st
rict formal analogy with the methods developed for equilibrium adsorpt
ion. The methods so developed are applied to the time-logarithm law us
ually referred to as the Elovich equation. (C) 1995 Academic Press, In
c.