Gy. Sung et Jd. Suh, NUCLEATION AND GROWTH OF B-AXIS ORIENTED PRBA2CU3O7-X THIN-FILMS ON LASRGAO4(100) SUBSTRATES, ETRI journal, 18(4), 1997, pp. 339-346
Good quality a-axis oriented thin films of YBa2Cu3O7-x may be grown by
the use of a PrBa2Cu3O7-x (PBCO) layer as a template. Here we present
a detailed study of the nucleation of the PBCO layer, explaining the
orientations observed. It is determined that the wavy surface of a LaS
rGaO4 (LSGO) (100) substrate consists of the {101} planes by observing
cross-sectional transmission electron microscopy images of the interf
ace between the PBCO film and the substrate. The images and selected a
rea diffraction patterns show that a mixed c- and b-axis oriented PBCO
layer was initially grown on the substrate, followed by pure b-axis o
riented PBCO growth. We explain that the c-axis oriented growth is the
result of the growth of the PBCO (019) planes on the LSGO (101) plane
s. We conclude that the nucleation and growth of the PBCO films at the
initial stages depends on the crystallographic plane of the substrate
surfaces, however, as the fi Im grows further, the kinetics of the de
position process favors b-axis oriented growth.