Cc. Geiger et al., ALIPHATIC-AROMATIC COPOLYCARBONATES DERIVED FROM 2,2,4,4-TETRAMETHYL-1,3-CYCLOBUTANEDIOL, Journal of polymer science. Part A, Polymer chemistry, 33(14), 1995, pp. 2317-2327
The synthesis of copolycarbonates with high aliphatic contents for pos
sible applications as optical plastics is described. Copolymers of 2,2
,4,4-tetramethyl-1,3-cyclobutanediol (TMCBD) with a series of 14 bisph
enol derivatives were prepared and characterized. The refractive index
of these materials varies from 1.49 for the 2,2-hexafluoropropane sub
stituted copolymer to 1.57 for the 9,9-fluorene substituted copolymer;
thus, all of the copolymers exhibit lower refractive indices than the
bisphenol A homopolycarbonate. The glass transition temperatures of t
he copolymers vary from 110 to 210 degrees C; the beta transition temp
eratures vary from -70 to 0 degrees C when measured at 10 Hz by dynami
c mechanical analysis. The copolymers exhibited good thermal stability
(0-3% weight loss) when heated above the glass transition temperature
, and only undergo extensive decomposition (80-90%) at 300-360 degrees
C. (C) 1995 John Wiley & Sons, Inc.