VELOCITY OF PROPAGATION IN REACTION-DIFFUSION FRONTS OF THE CHLORITE-TETRATHIONATE REACTION

Citation
A. Toth et al., VELOCITY OF PROPAGATION IN REACTION-DIFFUSION FRONTS OF THE CHLORITE-TETRATHIONATE REACTION, Journal of the Chemical Society. Faraday transactions, 93(1), 1997, pp. 73-76
Citations number
14
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
09565000
Volume
93
Issue
1
Year of publication
1997
Pages
73 - 76
Database
ISI
SICI code
0956-5000(1997)93:1<73:VOPIRF>2.0.ZU;2-G
Abstract
The effect of the initial concentration of reactants on the velocity o f chemical fronts in the acid-catalysed chlorite oxidation of tetrathi onate was investigated both numerically and experimentally. Based on a simple two-variable model an expression for front velocity as a funct ion of concentration and diffusion coefficient of reactants was develo ped which can quantitatively describe the observed velocity dependence in slight chlorite excess.